Phenyltrimethylammonium Functionalized Polysulfone Anion Exchange Membranes
نویسندگان
چکیده
منابع مشابه
Polysulfone-based Anion Exchange Membranes for Potential Application in Solid Alkaline Fuel Cells
In present research work, anion exchange membranes based on quaternized polysulfone with ammonium cation moieties (QAPSF) were prepared by chloromethylation, amination and alkalization. The chloromethylated polysulfone were characterized by 1HNMR spectroscopy and functionalization degree was determined according to peak area integration. Ion transport properties (ionic conductivity, ion exchang...
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Anion exchange membranes (AEMs) find widespread applications as an electrolyte and/or electrode binder in fuel cells, electrodialysis stacks, flow and metal-air batteries, and electrolyzers. AEMs exhibit poor stability in alkaline media; their degradation is induced by the hydroxide ion, a potent nucleophile. We have used 2D NMR techniques to investigate polymer backbone stability (as opposed t...
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In the current research, polyvinylchloride based mixed matrix heterogeneous anion exchange membranes were prepared by a solution casting technique. Titanium dioxide nanoparticles were also utilized as inorganic filler additive in the membrane fabrication. The effect of TiO2 nanoparticles concentration in the casting solution on the membrane physico-chemical properties was studied. Membrane wate...
متن کاملInvestigation of ion transport and water content properties in anion exchange membranes based on polysulfone for solid alkaline fuel cell application
In present research work, homogeneous anion exchange membranes based on polysulfone (QAPSFs) were prepared via chloromethylation, amination and alkalization. In amination step, trimethylamine and N,N,N',N'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. The chloromethylated polysulfone was characterized by 1HNMR spectroscopy and chloromethylation degr...
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in the current research, polyvinylchloride based mixed matrix heterogeneous anion exchange membranes were prepared by a solution casting technique. titanium dioxide nanoparticles were also utilized as inorganic filler additive in the membrane fabrication. the effect of tio2 nanoparticles concentration in the casting solution on the membrane physico-chemical properties was studied. membrane wate...
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ژورنال
عنوان ژورنال: Macromolecules
سال: 2012
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma202681z